Questions
INSTRUCTIONS TO CANDITATES
- All questions must be answered in English
- Answer all the questions in the spaces provided .All working must be clearly shown where necessary.
- Non programmable electronic calculators and logarithm tables may be used
- The grid below forms part of the periodic table. Study it and answer the questions that follow. The letters do not represent the actual symbols of the elements
- Write the general name given to the element P belong. (1mark)
- An element N has an atomic number of 15. Write down its electronic arrangement and hence fix it in its right position on the grid above. (2marks)
Electronic arrangement ………………………………………………………………………… - Compare the size of the atom of R and that of its ion. Explain your answer. (2marks)
- Give the formula of the compound formed between (1mark)
- P and W …………………………………………………………………………
- T and Y …………………………………………………………………………..
- Compare the melting points of element Q and S. Explain (2marks)
- State the least reactive element in the grid. Give a reason for your answer (2marks)
- Give two advantages that element S has over element Q in making electric cables(2mks)
- Draw (a) dot (.) and cross (x) diagram to represent the bonding in compound formed between T and Y (2 marks)
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- Study the flow chart below and answer the questions that follow.
- Name the process taking place in step (I). (1mark)
- Describe a chemical test that can be carried out to show the identity of organic compound (2marks)
- Give the name of the following: (2marks)
- Give the structural formulae of substance C. (1mark)
- Name the type of reaction that occurs in:
- Step IV (2marks)
- Step VI:
- Give the reagent and the condition necessary for step VI. (2marks)
- Reagent:…………………………………………………………………………………………………
- Condition:………………………………………………………………………………………………
- Give the systematic names of the following compounds:
- CH2CHCHCH2CH3 (1mark)
- CH C CH3 (1mark)
- Study the flow chart below and answer the questions that follow.
- The table below gives standard electrode potentials for the metals represented by the letters D, E, F and G. Study it and answer the questions that follow
- Which metal can be displaced from a solution of its salts by all the other metals in the table. Give a reason (2mks)
Metals Standard electrode potential (volts) D - 0.13 E -0.85 F + 0.34 G -0.76 -
- Draw a cell diagram when metal G and F are connected to form a full(3mks)
- Indicate on the diagram the direction of flow of electrons(1mk)
- Write an equation for the reaction that take place in G half cell(1mk)
- State two functions of a salt bridge (2mks)
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- State Faradays first law of electrolysis (1mk)
- A current of 2A was passed through copper (ii) Sulphate solution 1hour 30 minutes. Calculate the quantity of electricity required to deposit 1 mole of copper (3mks)
- State two application of electrolysis (1mk)
- Which metal can be displaced from a solution of its salts by all the other metals in the table. Give a reason (2mks)
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- Sodium metal is extracted using the downs cell.The anode is made of graphite and surrounded by a steel gauze cylinder. Describe briefly how this process is carried out. (3mks)
- Explain why the anode is
- Made of graphite (1mk)
- Surrounded by a steel gauze cylinder (1mk)
- State two properties of sodium metal that make it possible for it to be collected as shown in the diagram (2mks)
- Write an equation to show the products formed when sodium reacts with air (1mk)
- Nitrogen forms 78% of air by volume. Nitrogen is one of the raw materials used in the Haber process.
- Describe how nitrogen is obtained from liquid air. (2mks)
- List TWO sources of obtaining large volumes of hydrogen for industrial use.(2mks)
- Burning magnesium continues to burn in a gas jar containing Nitrogen
- Explain (1mk)
- Write an equation for the reaction taking place when the product is reacted with water (1mk)
- Name the catalyst used in the Haber process (1mk)
- A farmer has three plots each measuring 0.25 acres. He applied nitrogenous fertilizers as follows.
- plot A 250 kg of ammonium phosphate
- plot B 250 kg of urea CO(NH2)2
- Plot C 250kg of ammonium nitrate
Which plot received the highest nitrogen content? (3mks)
(H = 1, N = 14, 0 = 16. P = 31, C = 12.)
- The table below shows the solubility of lead ii nitrate and potassium nitrate at different temperatures. Study it and answer questions that follow
Temperature°C 0 20 40 60 80 100 Solubility of Pb(NO3) in g/100g of water 37.5 52.5 69.0 87.5 110.0 131.0 Solubility of KNO3 in g/100g of water 12.5 32.5 62.5 110.0 137.5 - On the same grid plot a graph of solubility of lead ii nitrate and potassium nitrate in g/100 of water against temperature in 0C(4mks)
- From the graph determine the point at which;
- The solubility of the two salts is the same (1mk)
- The solubility of lead ii nitrate is 58.0g/100g of water (1mk)
- The mass of the crystals that would be formed if the saturated solution was cooled from 800C to 300C (3mks)
- A water sample is suspected to contain lead (ii) ions. Describe how the presence of lead ions would be confirmed using sodium hydroxide solution and potassium iodide solution(2mks)
- A student set up the apparatus below for preparation and collection of dry hydrogen gas. Study it and use it to answer questions that follow
- Complete the set up to show dry hydrogen can be collected (3mks)
- The student identified substance K as Nitric V acid and L as zinc granules. Explain the student did not achieve the objective for experiment.(2mks)
- State the correction the student should make to achieve the objective (1mk)
- Hydrogen gas obtained was reacted with nitrogen gas as shown below
N2(g)+3H2(g) → 2NH3(g)- State and explain two factors that can alter the equilibrium constant above(3mks)
- Determine the number of moles of nitrogen gas used given that 300cm3 of hydrogen was used.(volume at STP =22.4L) (2mks)
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